Main > ORGANIC CHEMICALS > Aliphatics > Amine. > Mfg > Olefin > Hydroaminomethylation > Catalyst > Rh/Ir Catalyst

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MANUFACTURING In the present work, reaction of propene with CO & NH3 gives amines in 90% yield:
- Me-CH=CH2+CO+NH3+H2 = C4H9-NH2
The catalyst is a mix of Rh(I) & Ir(I) chelated by sulfonated 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl.
Rh leads to high selectivity &
Ir gives fast hydrogenation of the intermediate imine
UPDATE 08.99
AUTHOR This data is not available for free
LITERATURE REF. This data is not available for free

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