MANUFACTURING |
In the present work, reaction of propene with CO & NH3 gives amines in 90% yield: - Me-CH=CH2+CO+NH3+H2 = C4H9-NH2 The catalyst is a mix of Rh(I) & Ir(I) chelated by sulfonated 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl. Rh leads to high selectivity & Ir gives fast hydrogenation of the intermediate imine |
UPDATE | 08.99 |
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LITERATURE REF. | This data is not available for free |
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