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Product Fumaric Acid. Butane Oxidation. USA. B.

PATENT ASSIGNEE'S COUNTRY USA
UPDATE 07.99
PATENT ASSIGNEE This data is not available for free
PATENT CLAIMS Process for coproducing purified fumaric acid & maleic anhy
dride comprising
(a) Deriving a compn comprising molten maleic anhydride &
fumaric acid from a system for the catalytic oxidation of bu
tane by
(1) Deriving a stream comprising vapor phase MAN from
a system for the catalyticoxidation of butane
(2) Condensing a portion of said MAN vapor & separating
crude MAN thus formed from uncondensed MAN vapor
(3) Deriving aq soln of maleic acid by adding water to the
uncondensed maleic anh. vapor at a T sufficient to form
maleic acid without forming fumaric acid
(4) Dehydrating the maleic acid soln & recovering a crude
maleic anh. stream & a dehydrator bottoms stream com
prising molten maleic anh. & fumaric acid
(b) Cooling the dehydrator bottoms stream to T sufficient to
precipitate the fumaric acid
(c) Separating the fumaric acid ppcc from (b) from the molten
maleic anh., removing residual maleic anh. from the fuma
ric acid ppcc, & recovering purified fumaric acid &
(d) Distilling crude maleic anh. stream obtained in (a4) & the
crude maleic anh, obtained in (a2) to obtain pure maleic
anh.
PATENT PHOTOCOPY Available on request

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